Long chain molecules
The molecules of thermoplastics are in lines or
long chains with very few entanglements. When heat is applied
the molecules move apart, which increases the distance between
them, causing them to become untangled. This allows them to become
soft when heated so that they can be bent into all sorts of shapes.
When they are left to cool the chains of molecules cool, take
their former position and the plastic becomes stiff and hard again.
The process of heating, shaping, reheating and reforming can be
repeated many times.